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Chemical Reactions on Polymers by Judith L. Benham, James F. Kinstle

By Judith L. Benham, James F. Kinstle

content material: amendment of condensation polymers : demanding situations and possibilities / William H. Daly, Soo Lee, and C. Rungaroonthaikul --
Dimethylene spacers in functionalized polystyrenes / Graham D. Darling and Jean M.J. Fréchet --
Chemical amendment of poly(vinyl chloroformate) by means of phenol utilizing phase-transfer catalysis / S. Boivin, P. Hemery, and S. Boileau --
Chemical amendment of poly(2,6-dimethyl-1,4-phenylene oxide) and homes of the ensuing polymers / Simona Percec and George Li --
Synthesis and reactions of halogenated polyethers and polysulfides / Melvin P. Zussman, Jenn S. Shih, Douglas A. Wicks, and David A. Tirrell --
Polymeric dialkylaminopyridines as supernucleophilic catalysts / Subhash C. Narang, Susanna Ventura, and Roopram Ramharack --
Styrenic- and acrylic-siloxane block and graft copolymers / S.D. Smith, G. York, D.W. Dwight, and J.E. McGrath --
impact of the polymer spine at the thermotropic habit of side-chain liquid crystalline polymers / Coleen Pugh and Virgil Percec --
Polyimidazolinones through thermal cyclodehydration of polyamides containing [alpha]-amino acid devices / Jerald okay. Rasmussen, Larry R. Krepski, Steven M. Heilmann, Kumars Sakizadeh, Dean M. Moren, Howell okay. Smith, II, and Alan R. Katritzky --
Synthesis and characterization of N-phenyl-3,4-dimethylenepyrrolidine polymers / Raphael M. Ottenbrite and Herbert Chen --
Polycyclopropanone synthesis and hydrogenolysis / Roderic P. Quirk and James H. Dunaway --
Chain-propagation and step-propagation polymerization : synthesis and characterization of poly(oxyethylene)-b-poly(pivalolactone)telechelomer / K.B. Wagener and S. Wanigatunga --
amendment of polymer surfaces by means of photoinduced graft copolymerization / B. Rånby, Z.M. Gao, A. Hult, and P.Y. Zhang --
Photoozonization of polypropylene : oxidative reactions brought on by ozone and atomic oxygen on polymer surfaces / J.F. Rabek, J. Lucki, B. Rånby, Y. Watanabe, and B.J. Qu --
Photochemical alterations of poly(vinyl chloride) : accomplishing polymers and photostabilization / C. Decker --
Hydrophilization of polydiene surfaces by way of low-temperature ene reactions / Lee A. Schechtman --
floor heparinization of poly(ethylene terephthalate) movies converted with acrylic hydrogels / Cristofor I. Simionescu, Monica Leanca, and Ioan I. Negulescu --
Reactions of steel vapors with polymers / Colin G. Francis, Scott Lipera, Pascale D. Morand, Peter R. Morton, John Nash, and Peter P. Radford --
Synthesis and characterization of block copolymers containing acid and ionomeric functionalities / T.E. lengthy, R.D. Allen, and J.E. McGrath --
AB block copolymers containing methacrylic acid and/or steel methacrylate blocks : practise via selective cleavage of methacrylic esters / Douglas E. Bugner --
Imide hydrolytic balance of N-substituted dimethacrylamide cyclopolymers : poly[N-(4-sulfophenyl)dimethacrylamide] / Joseph J. Kozakiewics, Sun-Yi Huang, Daniel R. Draney, and JoAnn L. Villamizar --
Radical-promoted functionalization of polyethylene : managed incorporation of hydrogen-bonding teams / M.F. Schlecht, E.M. Pearce, T.K. Kwei, and W. Cheung --
fresh reviews of polymer reactivity / Herbert Morawetz --
Analytical examine of photodegraded p-aramid in an ¹⁸O₂ surroundings / Madeline S. Toy and Roger S. Stringham --
response of atomic oxygen [O(³P)] with polybutadienes and comparable polymers / Morton A. Golub, Narcinda R. Lerner, and Theodore Wydeven --
Tri-n-butyltin hydride relief of poly(vinyl chloride) : kinetics of dechlorination for 2,4-dichloropentane and 2,4,6-trichloroheptane / Fabian A. Jameison, Frederic C. Schilling, and Alan E. Tonelli --
identity of goods from polyolefin oxidation by way of derivatization reactions / D.J. Carlsson, R. Brousseau, Can Zhang, and D.M. Wiles --
Catalytic hydrogenation, hydroformylation, and hydroxymethylation of polybutadiene : synthesis and characterization / N.A. Mohammadi and G.L. Rempel --
Reactive modifiers for polymers / S. Al-Malaika --
Phase-transfer-catalyzed amendment of dextran applying dibutyltin dichloride and bis(cyclopentadienyl)titanium dichloride / Yoshinobu Naoshima and Charles E. Carraher, Jr. --
Cross-linking of ethylene-propylene copolymer rubber with dicumyl peroxide-maleic anhydride / Norman G. Gaylord, Mahendra Mehta, and Rajendra Mehta --
Synthesis of conjugated polymers through polymer removing reactions / Samson A. Jenekhe --
Cross-linking and isomerization reactions of an acetylene-terminated polyisoimide prepolymer / R.H. Bott, L.T. Taylor, and T.C. Ward.

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Phase-Transfer Catalysis 45 4. ; IRIE,S. J. Polym. Sci. Polym. Chem. Ed. 1973, 11, 789. 5. A. J. Polym. Sci. Polym. Phys. Ed. 1974, 12, 1711. 6. ; LOUCHEUX,C. Makromol. Chem. 1975, 176, 315. 7. C. J. Chem. Soc. ; KHOSRAVIBABADI, E. J. Chem. Soc. Faraday Trans. 1 1983, 79, 1951. 8. C. C. Polymer 1982, 23, 1493. 9. A. Pure Appl. Chem. 1976, 46, 49. 10. ; SMETS,G. J. Polym. Sci. 1959, 40, 203. 11. C. J. Polym. Sci. A-1 1968, 6, 2433. 12. ; BARTH,V. Polymer 1976, 17, 777, 787. 13. E. Am. Chem Soc Polym Prep 1986 27(2) 57 14.

ACS Symposium Series; American Chemical Society: Washington, DC, 1988. 26 CHEMICAL REACTIONS ON POLYMERS r e s o n a t i n g w i t h r e a c t i o n p r o d u c t s , make many non-metal atoms e a s i e r t o o x i d i z e . More e l e c t r o p o s i t i v e elements, such as s i l i c o n ( 4 0 ) , a r e e a s i l y d i s p l a c e d from phenyl by p r o t o n s and o t h e r L e w i s a c i d s through e l e c t r o p h i l i c a r o m a t i c s u b s t i t u t i o n . Furthermore, an a n t i p o d a l e l e c ­ t r o n - w i t h d r a w i n g group can a c t i v a t e b e n z y l hydrogen on t h e polymer backbone f o r i n o p p o r t u n e i o n i c o r r a d i c a l s i d e - r e a c t i o n s ( 4 1 ) .

In order to explain why the chloroformate functions belonging to i s o t a c t i c sequences are the most reactive, further work i s presently undertaken concerning the study of the conformational structure of PV0CC1 macromolecules i n solution. Along the same l i n e , i t would be interesting to examine some substitution reactions of trimeric models having different stereoconfigurations. Moreover i t would be worth extending this preliminary study to the examination of the behaviour of PV0CC1 samples with different t a c t i c i t i e s .

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