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Catalysis: A Review of recent literature by James J Spivey; C Cristiani; Royal Society of Chemistry

By James J Spivey; C Cristiani; Royal Society of Chemistry (Great Britain); et al

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Chem. 88 (1984) 427. , Ber. Bunsenges. Phys. Chem. 91 (1987)1007. , Appl. Catal. 30 (1987)277. , Appl. Catal. 65 (1990)241-252. , Catalysis Today 9 (1991)153-160. , Thesis, University of Karlsruhe, 1987. -G. (eds), Proc. 8th Intl. Symp. on Reactivity of Solids, Plenum Press, New York, 1977,p161. , Gazz. Chim. Ztal. 110 (1980)389. , J. Electrochem. 140 (1993)1677-1681. , “Instrumental Methods in Electrochemistry”, Southampton Electrochemistry Group, 1985. , J. Electrochem. 126 (1979) 2183-7. , J.

Similarly when the pre-reduced surface was exposed to a low partial pressure of CO low amplitude oscillations were observed with a high baseline oxygen activity close to that of the pre-oxidised case. Unlike the pre-oxidised case, when the partial pressure of oxygen was increased, the baseline oxygen activity remained approximately constant; the amplitude of oxygen activity excursions increased as did their frequency. Vayenas and coworkers studied the synchronization of the oscillations by investigating the behaviour of two electrodes.

Metcalfe and Sundaresan were able to show that this was the only cathodic reaction taking place under CO rich conditions. 6), as in the oxygen rich regime. e. the electrochemical reactions allow carbon monoxide adsorbed on the platinum to react with oxygen adsorbed on the surface of the electrolyte.? This process was shown to be of a sufficient magnitude that it may modify the behaviour of a catalyst if small platinum crystallites (10-50 were present. Lintz and co-workers have investigated the effect of a bismuth additive in metal electrodes for carbon monoxide oxidation56 and have also used SEP to study carbon monoxide ~ x i d a t i o n .

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