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Advanced Inorganic Chemistry. A Comprehensive Text by Cotton F.A., Wilkinson G.

By Cotton F.A., Wilkinson G.

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For additional results see ref. ) A few complexes other than the organic chelates have been reported to luminesce. For all of these the emission is of the d-d type. Trans[Ru(dpp),CI,] and tv~ns-[Os(dpp)~Cl,]exhibit somewhat peculiar emission behavior, compared to all other known metal complex luminophores. These species are reported to fluoresce from two excited singlet states, lA,, and lEg, both derived from one 'TI, level of O,, symmetry (1 13). The primary difference between these emissions and those of other metals is that they do not originate in the lowest excited state of the molecules.

An uncertain value obtained from the excitation spectrum of emission, ref. 150. Limiting anation quantum yield for reaction (33). Quantum yield is wavelength- and temperature-dependent. Oxygen-sensitive reaction. It is not known whether these bands are singlet or triplet transitions. 97 kK). 41 k K ) . 8:l. + Pt(dien)Br + Pt(dipy)zz Pt(dipy)Clz trans-Pt(g1y)z cis-Pt(gly), PtCI,(C,H,) - cis-Pt(etm)2C1z PtC1*2 - Complex TABLE X Luminescence and Photochemistry of Platinum(I1) Complexes 46 P. D. FLEISCHAUER, A.

2. 4) is related to reaction from a CT state, as suggested in the flash photolysis studies (103). The proof (for or against) of alternative 1 may well be determined by the use of photosensitizers in this system. A donor whose singlet and triplet levels lie between 13,500 and 19,000 cm-’ should efficiently sensitize the substitution reaction if alternative 1 is correct. The increasing complexity in studies of complexes of heavier (second and third row) metals is especially evident for platinum. The spin-orbit coupling for these metals is so large that distinction between singlet and triplet states is sometimes very difficult.

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